Chemistry of polyurethane coatings

- 2024-08-30-

Polyurethane coatings are widely used for coating various surfaces. Their chemical properties make them excellent in durability and functionality. Here are some of the main chemical properties of polyurethane coatings:


1. Chemical structure

Composition of polyurethane: Polyurethane coatings are made by reacting polyester or polyether polyols and isocyanates. Polyols and isocyanates are linked by urethane bonds to form polyurethane chains.

Chain structure: The molecular chains of polyurethane can be linear, cross-linked, or have other structural features that affect their final performance.


2. Cross-linking and hardening

Cross-linking reaction: Polyurethane coatings form a three-dimensional network structure during the curing process through cross-linking reactions. This structure provides excellent resistance to wear, chemicals, and weathering.

Curing: After the coating is applied, the cross-linking reaction will occur, and a certain amount of time and temperature are usually required to complete the curing process.


3. Chemical resistance

Solvent resistance: Polyurethane coatings have good resistance to many organic solvents and are suitable for coating surfaces that need to be resistant to chemicals.

Acid and alkali resistance: Polyurethane coatings are also relatively resistant to some acids and alkalis, but the specific resistance depends on the specific formulation.


4. Weatherability

UV stability: Some polyurethane coatings have good UV resistance and can maintain stability for a long time in sunlight without fading or degradation.


Temperature resistance: Polyurethane coatings can generally withstand a wide range of temperatures, but the specific temperature resistance depends on its specific formulation and application environment.


5. Adhesion and elasticity

Adhesion: Polyurethane coatings have good adhesion to a variety of substrates, including metal, wood, concrete, etc.

Elasticity: They also have excellent elasticity and flexibility, and can resist mechanical stress and deformation.


6. Abrasion resistance

Surface hardness: The cured polyurethane coating has a high surface hardness and excellent wear resistance, making it suitable for coating floors, vehicles and equipment.


7. Environmental protection and safety

VOC (volatile organic compounds): Traditional polyurethane coatings may contain high concentrations of VOCs, which have potential impacts on the environment and health. Modern formulations are constantly improving, and low-VOC or VOC-free polyurethane coatings have been developed.


8. Construction performance

Applicability: Polyurethane coatings can be applied by brushing, spraying, dipping and other methods, and usually have good leveling properties.

Drying time: Drying time depends on the formulation and environmental conditions. Generally, curing takes a certain amount of time to achieve optimal performance.


In general, polyurethane coatings are widely used in many fields such as construction, industry, and automobiles due to their excellent chemical and physical properties.